Product ID:PRINCAP 80W
MSDS Date:10/12/1993
FSC:6840
NIIN:00-814-7334
Status Code:A
MSDS Number: CHYZF

CIBA-GEIGY CORP, AGRICULTURAL DIV.

410 SWING ROAD
GREENSBORO, NC 27419
US

Emergency Phone: 800-888-8372/800-424-9300(CHEMTREC)

Info Phone: 919-292-7100

Cage: 8K340

CIBA-GEIGY CORP, AGRICULTURAL DIV.

18300 GREENSBORO, NC 27419

Telephone: 800-888-8372 OR 800-334-9481

Cage: 8K340

CRYSTALLINE SILICA

RTECS: 9999999ZZ

ETHYLENE GLYCOL (SARA 313) (CERCLA)

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 24%

ACGIH TLV: C STEL39PPM,A4,VAP96

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

DUSTS, NUISANCE

2-CHLORO-4,6-BIS(ETHYLAMINO)-S-TR1AZINE; SIMAZINE

CAS: 122-34-9

RTECS: XY5250000

Fraction By Weight: 83%

LD50 LC50 Mixture:ORAL LD50(RAT):>15380 MG/KG BODY WT
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INGEST:PRACTICALLY NON-TOXIC.BASED ON
ACUTE ORAL LD50 IN RATS INGEST OF FATAL DOSE OF PRINCEP 80W BY
PERSON IS UNLIKELY.DERM ABSORP:PRACTICALLY
NON-TOXIC.INHAL:MODERATELY TOXIC.EYE:SLIGHTLY IRRIT(RABB
IT).SKIN:MINIMALLY IRRIT (RABBIT).SKIN SENSITIZATION:NOT
SENSITIZER(GUINEA PIG).
Explanation of Carcinogenicity:PER MSDS:IARC LISTED CRYSTALLINE SILICA
AS PROBABLE HUMAN CARCINOGEN(CLASS @).
Effects of Overexposure:OVEREXPO TO PRINCEP 80W MAY RESULT IN IRRIT
EYES/SKIN/NOSE/THROAT.IF LG AMT INGEST NAUSEA OR VOMIT MAY
OCCUR.SEVERE KIDNEY DMG RESULTS FRM INGEST LG VOLUMES OF ETHYLENE
GLYCOL.CHRONIC INHAL EXPO TO CR YSTALLINE SILICA IS KNOWN TO CAUSE
SILICOSIS & PULM FIBROSIS IN HUMANS.PROL BREATH OF EXCESS DUST MAY
AFFECT LUNG FUNCTI
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING
RESPIRATORY DISORDERS SHOULD USE EXTRA CARE IN HNDLG THIS PRODUCT.

First Aid:IF POISONING IS SUSPECTED IMMED CONTACT DR/NEAREST
HSOP/NEAREST POIS CNTRL CNTR.TELL PERONS CONTACTED COMPLETE PRODUCT
NAME/TYPE/AMT OF EXPOSURE.DESCRIBE ANY SYMPTOMS & FOLLOW ADVICE
GIVEN.INGEST:FULL Y CONSC IMMED GIVE 1-2GLASSES OF H2O
TODRINK,INDUCE VOMIT.NEVER GIVE ANYTING BY MOUTH IF UNCONSC.APPLY
ART RESP IF NECESSARY.EYE:IMMED RINSE W/LG AMT OF RUNNING H2O.HOLD
EYELIDS APART.DONT APPLY(SUP)

Flash Point:NA
Autoignition Temp:Autoignition Temp Text:NA
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:USE DRY CHEM,FOAM,CO2,EXTINGUISHING MEDIA.
Fire Fighting Procedures:WEAR FULL PROT CLOTH & SELF-CONTAINED BREATH
APPARATUS.EVACUATE NONESSENTIAL PERSONNEL FROM AREA TO PREVENT
HUMAN EXPO TO FIRE/SMOKE/FUMES/PRODS OF COMBUST.
Unusual Fire/Explosion Hazard:THIS PRODUCT PRESENTS A POSSIBLE DUST
EXPLOSION HAZARD AT TEMPS ABOVE 110C.PREVENT USE OF CONTAM
BUILDINGS,AREAS,EQPMT TIL DECONTAM.

Spill Release Procedures:WEAR CHEM SAF GLASS/GOG,RUBB GLOVE/BOOT,LONG
SLEEVE SHIRT,LONG PANTS,HAT,NIOSH APPROV DUST/PESTICIDE
RESP.SM:SWEEPUP,KEEP DUST MIN,PLACE IN APPROV CHEM CNTNR.WASH AREA
W/H2O&STRONG DTRGNT,ABSORB W/PET LITTER/OTHER ABSORB.SWEEPUP,PLACE
IN(OTH PRECAU)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE MATL IN WELL VENTI SECURE AREA
OUT OF REACH OF CHILDREN/DOMESTIC ANIMALS.DONT STORE
FOOD/BEV/TOBACCO PROD IN STORAGE AREA.
Other Precautions:PREVENT EAT/DRINK/TOBACCO USE/COSMETIC APPLICATION IN
ARAS WEHRE POT FOR EXPO TO MATL.SPILL:IN CHEM CNTNR.SEAL CNTNR,HNDL
IN APPROV MANNER.FLUSH SPILL AREA W/H2O TO REMOVE ANY RESIDUE.DONT
ALLOW WASH TO CONTAM H2O SUPPLIES.

Respiratory Protection:TO AVOID BREATH DUST WEAR NIOSH APPROVED
DUST/PESTICIDE RESPIRATOR.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:RUBBER GLVOES
Eye Protection:CHEMICAL SAFETY GLASSES OF GOGGLES
Other Protective Equipment:RUBBER BOOTS,LONG-SLEEVED SHIRT,LONG
PANTS,HAT.
Work Hygienic Practices:WASH CONTAM CLOTH BEF REUSE.ALWAYS WASH WELL
AFT HNDLG.
Supplemental Safety and Health
1STAID:MED AGENTS EXCEPT ON DR ADVICE.SKIN:WASH W/LOTS OF SOAP/H2O
INCLUDE HAIR/UNDER FINGERNAILS.DONT APPLY MED AGENTS EXCEPT ON DR
ADVICE.REMOVE CONTAM CLOTH.INHAL:MOVE TO FRESH AIR.APPLY ART RESP I
F NECESSARY.DR NOTES:NO SPEC ANTIDOTE.LG AMT INGEST & EMESIS
INADEQU LAVAGE STOMACH.5MG/KG CHARCOAL TO ABSORB TOXICANT.

HCC:T5
Boiling Pt:B.P. Text:NA
Melt/Freeze Pt:M.P/F.P Text:437F,225C
Decomp Temp:Decomp Text:NP
Vapor Pres:1.07X10-7
Vapor Density:NP
Spec Gravity:1.48 @20C
pH:NA
Viscosity:NP
Evaporation Rate & Reference:NA
Solubility in Water:INSOLUBLE
Appearance and Odor:WHITE TO TAN POWDER, ODORLESS
Percent Volatiles by Volume:NP
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE KNOWN
Hazardous Decomposition Products:UPON DECOMPOSITION,PRINCEP 80W
RELEASES A FLAMMABLE GAS.

Waste Disposal Methods:SARA TITLE III SEC 313 CHEM PRESENT:ETHYLENE
GLYCOL.NO RQ/RCRA.DONT REUSE PROD CNTNR.DISPO OF PROD CNTNR/WASTE
CNTNR/RESIDUE ACCORDING TO LOC/STATE/FED HEALTH/ENVIRO
REGS.QUESTIONS ON SAFE HNDLG OF MA TL SHOULD BE REFER TO CIBA-GEIYA
CORP 800-334-9481

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.